Samuel Thompson @SamuelThomp2000
Chemistry PhD Student🧪 Stasch Group St Andrews, UK. London, England Joined June 2022-
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Come and visit London’s Home of Trophies. 🏆 Book your Stadium Tour at Stamford Bridge now. ⭐️⭐️
Kraken the Mg(0) code: Yixiao, Maryam and Sophie's ink-credible paper on a TCHP substituted analogue of Harders's heavily-armed Mg(0) cmpd, high yields of Mg(0)/Mg(I) clusters, and their redn of TM carbonyls, has been accepted @ChemicalScience. tinyurl.com/569xhww2 #ozchem
We have also had a recently accepted paper with the Stasch group in @ChemEurJ (doi.org/10.1002/chem.7…). This investigates main-group complexes of a new iminophosphorane-based scorpionate ligand. We determined the structures of fourteen ligands and complexes. @StAndrewsChem
Our review article setting out strategies for the chemical recycling of fluorocarbons - including refrigerants, fluoropolymers, and PFAS - is now out in @NatRevChem congrats to @shannon_esf1 and thanks to our fantastic editorial team @stephgreed. rdcu.be/e9vZD
MOLECULAR ZINTL PHASES with tetra-anionic Si, Ge, Sn, Pb accessible using soluble Mg(0). Although all E(4-) anions are full valence-shell octets, they are highly reactive. The Sn(-IV) complex is an 8e-reductant @FAU shorturl.at/InmD6 @NatureSynthesis
We have a recently accepted paper with the Stasch group in @Orgmet_ACS (doi.org/10.1021/acs.or…). We determined the structures of ten complexes of gallium with new ligands, as well as various reaction products. @StAndrewsChem
Want to read about some of the highlights in the broad field of coordination chemistry from 2025? Look no further! gdch.app/article/nebeng… Put together by myself and (Twitterless) Gabi Hierlmeier 🧪
Great to see this out! Fabian (@danke2t) and I summarise some of our favourite papers in main group chemistry over the last year gdch.app/article/hauptg…
FINALLY a complex of type LMg-CaL! This formally Mg(0)-Ca(II) complex shows a very long Mg-Ca bond with Mg(-)/Ca(+) polarization and is quite reactive! Our first 2026 paper is "In dear memory of Herbert Roesky" shorturl.at/tvi0C
@Jones_Research @InorgChem @AFOSR @ChemistryMonash Nice work!
Jeremy's latest (of many) papers on the Mg(I) reduction of nitrogen oxides, N2O and a NO source, has been accepted @InorgChem. Part of an upcoming special issue on MG chem. #ozchem @AFOSR @ChemistryMonash #maingroupchemistry tinyurl.com/mryc2ump
The group will soon be advertising a 3-year PDRA position @impchemistry. The successful candidate will research the synthesis and reactivity of complexes with alkaline earth-metal bonds. Start date: 03/26. Please get in touch for infomal inquries.
A paper accepted late at the end of last year is this work with the Stasch group published in @DaltonTrans (doi.org/10.1039/D5DT02…). We determined the structures of five calcium complexes, including a donor-solvent-free molecular calcium hydride complex. @StAndrewsChem
What happens when you put 3 redox-active metal centers together? 🧪 @lapluhp demonstrates the simultaneous, cooperative activation of an alkene and dihydrogen in a single complex 🤯 plus in-depth kinetic analyses and catalysis. Beautiful work Till! tinyurl.com/5xrfzkk5
One is a red card 🟥 One is a yellow card 🟨
Estevao Willian.
TIRE CHANGE: First Mg(I) complex with a Cp* ligand enables facile ligand exchange. Reaction with RONa gives (BDI)Mg-MgOR and Cp*Na. This paves the way for syntheses of many new asymmetric Mg(I) complexes. @angew_chem onlinelibrary.wiley.com/doi/epdf/10.10…
In 2017, Mike Hill and team published the remarkable nucleophilic alkylation of benzene with neutral calcium alkyl complexes. Here we report their anionic equivalents, and show a switch in reactivity to superbasic - deprotonating benzene, twice! doi.org/10.1002/anie.2…
REDOX-REACTIVITY of Yb and Sm inverse sandwich benzene complexes. An interesting observation is that, depending on substrate, benzene(4-) can reduce Sm(III) to Sm(II). doi.org/10.1002/chem.2…
A PDRA position is available @BathChem in the Liptrot group. Great opportunity with a fantastic group! bath.ac.uk/jobs/Vacancy.a…
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